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Título : | Three structural modifications in the series of layered solids T(H2O)2[Ni(CN)4]·xH2O with T = Mn, Co, Ni: Their nature and crystal structures |
Palabras clave : | 2D SOLIDS CRYSTAL STRUCTURE TETRACYANIDE |
Fecha de publicación : | 16-ene-2013 |
Editorial : | ELSEVIER |
Descripción : | In the studied series of layered solids, the available coordination sites at T metal centers are occupied by water molecules which serve to stabilize additional water molecules in the interlayer region through hydrogen bonding interactions. The stability of these 2D solids results from these interactions between coordinated and weakly bonded water molecules. In this contribution, the crystal structures and related properties of the titled compounds are reported. Three different structural modifications for a given T metal were found. The refined crystal structures were supported by the recorded infrared, Raman, and UV–vis spectra and thermogravimetric data. Two of these modifications were found to be room and high temperature thermodynamic products and the remaining one a room temperature kinetic product. Projects SEP-CONACyT- 2009-01-129048 and 2010-01-155413 |
URI : | http://www.repositoriodigital.ipn.mx/handle/123456789/10585 |
Otros identificadores : | CR CHIMIE IN PRESS DOI:10.1016/ j.crci.2011.11.004 1631-0748 http://hdl.handle.net/123456789/45 |
Aparece en las colecciones: | Doctorado |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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2011 CRC Lemus-Santana Three structural modifications.pdf | 802.71 kB | Adobe PDF | Visualizar/Abrir |
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