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http://repositoriodigital.ipn.mx/handle/123456789/11133Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | LEMUS SANTANA, A.A. | - |
| dc.creator | RODRIGUEZ HERNANDEZ, J. | - |
| dc.creator | DEL CASTILLO, L.F. | - |
| dc.creator | BASTERRECHEA, M. | - |
| dc.creator | REGUERA, E. | - |
| dc.date | 2012-03-27T21:32:43Z | - |
| dc.date | 2012-03-27T21:32:43Z | - |
| dc.date | 2009-01-08 | - |
| dc.date.accessioned | 2013-01-16T12:51:44Z | - |
| dc.date.available | 2013-01-16T12:51:44Z | - |
| dc.date.issued | 2013-01-16 | - |
| dc.identifier | Journal of Solid State Chemistry 182 (2009) 757–766 | - |
| dc.identifier | http://hdl.handle.net/123456789/644 | - |
| dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/11133 | - |
| dc.description | The materials under study, T[Ni(CN)4] 2pyz with T ¼ Mn, Zn, Cd, were prepared by separation of T[Ni(CN)4] layers in citrate aqueous solution to allow the intercalation of the pyrazine molecules. The obtained solids were characterized from chemical analyses, X-ray diffraction, infrared, Raman, thermogravimetry, UV–Vis, magnetic and adsorption data. Their crystal structure was solved from ab initio using direct methods and then refined by the Rietveld method. A unique coordination for pyrazine to metal centers at neighboring layers was observed. The pyrazine molecule is found forming a bridge between Ni and T atoms, quite different from the proposed structures for T ¼ Fe, Ni where it remains coordinated to two T atoms to form a vertical pillar between neighboring layers. The coordination of pyrazine to both Ni and T atoms minimizes the material free volume and leads to form a hydrophobic framework. On heating the solids remain stable up to 140 1C. No CO2 and H2 adsorption was observed in the small free spaces of their frameworks. & 2009 Elsevier Inc. All rights reserved. | - |
| dc.language | en | - |
| dc.publisher | Journal of Solid State Chemistry | - |
| dc.subject | Crystal chemistry | - |
| dc.subject | Structural studies | - |
| dc.subject | Layered compounds | - |
| dc.subject | Pillared solids | - |
| dc.title | Unique coordination of pyrazine in T[Ni(CN)4] 2pyz with T ¼ Mn, Zn, Cd | - |
| dc.type | Article | - |
| Aparece en las colecciones: | Doctorado | |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 2009JSSChPyrazine 2.pdf | 82.38 kB | Adobe PDF | Visualizar/Abrir |
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