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http://repositoriodigital.ipn.mx/handle/123456789/11158Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | RODRIGUEZ HERNANDEZ, J. | - |
| dc.creator | AVILA, M. | - |
| dc.creator | REGUERA, E. | - |
| dc.date | 2012-03-27T22:44:32Z | - |
| dc.date | 2012-03-27T22:44:32Z | - |
| dc.date | 2008 | - |
| dc.date.accessioned | 2013-01-16T13:04:22Z | - |
| dc.date.available | 2013-01-16T13:04:22Z | - |
| dc.date.issued | 2013-01-16 | - |
| dc.identifier | http://hdl.handle.net/123456789/672 | - |
| dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/11158 | - |
| dc.description | When in the titled materials the 3D framework is formed by practically linear T-N-C-M-C-N-T chains, they are known as Prussian blue (PB) analogues where the two metal centers have octahedral coordination. PB analogues crystallize with a cubic unit cell. However, for different combinations of T and M metals deviations from that regularity are observed, particularly for the T metal coordination modes. The metal M is always found with an octahedral coordination to form the octahedral anionic building block, [Mn(CN)6]n¡6. In this contribution such deviations or atypical coordination modes are summarized. The coordination for the T metal determines many of the solid physical properties, among them the porous framework, the magnetic interaction between metal centers, and the thermal stability. Atypical coordination modes for the metal T were observed for T = Zn with M = FeII , RuII , OsII ; FeIII , CoIII , RhIII and IrIII , and for Mn(2+) and Cd(2+) with M = FeII , RuII , OsII . | - |
| dc.language | en | - |
| dc.publisher | Brazilian Synchrotron Light Laboratory | - |
| dc.title | Atypical Coordination in Transition Metal Hexacyanometallates | - |
| dc.type | Article | - |
| Aparece en las colecciones: | Doctorado | |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 2008LNLSReportAtyplicalCoord 1.pdf | 335.3 kB | Adobe PDF | Visualizar/Abrir |
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