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http://repositoriodigital.ipn.mx/handle/123456789/11660Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | GOMEZ, A. | - |
| dc.creator | LARA, V.H. | - |
| dc.creator | BOSCH, P. | - |
| dc.creator | REGUERA, E. | - |
| dc.date | 2012-03-29T21:42:57Z | - |
| dc.date | 2012-03-29T21:42:57Z | - |
| dc.date | 2002-06 | - |
| dc.date.accessioned | 2013-01-16T16:34:53Z | - |
| dc.date.available | 2013-01-16T16:34:53Z | - |
| dc.date.issued | 2013-01-16 | - |
| dc.identifier | Powder Diffraction 17 (2), June 2002 | - |
| dc.identifier | http://hdl.handle.net/123456789/1228 | - |
| dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/11660 | - |
| dc.description | The crystal structures of two manganese hexacyanometallates~II!, Mn2 @Fe(CN)6#.8H2O and Mn2@Os(CN)6#.8H2O, were refined from X-ray powder diffraction data using the Rietveld method, with the reported structure for Mn2@Ru(CN)6#.8H2O used as a structural model. These compounds are isomorphous and crystallize in the monoclinic space group P21 /n. Their crystallization water is not firmly bound and can be removed without disrupting the M–CwN–Mn network. In the dehydrated complexes, the outer cation ~Mn! remains linked to only three N atoms from CN ligands while the inner cation ~Fe,Os! preserves its coordination sphere. The IR, Raman, and Mo¨ssbauer spectra for the hydrated and anhydrous forms are explained based on the refined structures. © 2002 International Centre for Diffraction Data. @DOI: 10.1154/1.1469023# | - |
| dc.language | en | - |
| dc.publisher | Powder Diffraction | - |
| dc.subject | ferrocyanide | - |
| dc.subject | infrared | - |
| dc.subject | osmocyanide | - |
| dc.subject | X-ray diffraction | - |
| dc.subject | Rietveld method | - |
| dc.subject | Mo¨ssbauer | - |
| dc.subject | Raman | - |
| dc.title | The structure of two manganese hexacyanometallates II : Mn2 Fe CN 6 .8H2O and Mn2 Os CN 6 .8H2O | - |
| dc.type | Article | - |
| Aparece en las colecciones: | Doctorado | |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 2002PDMn2OsFe 1.pdf | 17.91 kB | Adobe PDF | Visualizar/Abrir |
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