Mechanochemical synthesis of hemin±imidazole complexes

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Campo DC	Valor	Lengua/Idioma
dc.creator	PENEQUE, ARMANDO	-
dc.creator	FERNANDEZ BERTRAN, JOSE	-
dc.creator	REGUERA, EDILSO	-
dc.creator	YEE-MADEIRA, HERNANI	-
dc.date	2012-03-29T21:56:00Z	-
dc.date	2012-03-29T21:56:00Z	-
dc.date	2000-04-03	-
dc.date.accessioned	2013-01-16T16:42:07Z	-
dc.date.available	2013-01-16T16:42:07Z	-
dc.date.issued	2013-01-16	-
dc.identifier	Transition Metal Chemistry 26: 76±80, 2001.	-
dc.identifier	http://hdl.handle.net/123456789/1233	-
dc.identifier.uri	http://www.repositoriodigital.ipn.mx/handle/123456789/11694	-
dc.description	Solid state reactions of hemin and imidazole were performed by milling the crystalline materials in an agate mortar. The process was monitored by i.r., x.r.d. and MoÈ ssbauer spectroscopies. Samples with di erent hemin to imidazole molar ratios were studied. The interactions of imidazole with the central Fe atom and with the propionic acid groups in the periphery of the hemin molecule were detected. The latter interactions are suppressed by washing with MeOH. Complexes with 1:2 and 1:4 hemin-to-imidazole molar ratios were identi®ed.	-
dc.language	en	-
dc.publisher	Transition Metal Chemistry	-
dc.title	Mechanochemical synthesis of hemin±imidazole complexes	-
dc.type	Article	-
dc.type	Book	-
Aparece en las colecciones:	Doctorado

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