Structural Characterization of Cadmium Hexacyanometallates(II) and Related Complexes

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Campo DC	Valor	Lengua/Idioma
dc.creator	REGUERA, E.	-
dc.creator	GOMEZ, A.	-
dc.creator	BALMASEDA, J.	-
dc.creator	CONTRERAS, G.	-
dc.creator	ESCAMILLA, A.	-
dc.date	2012-03-29T22:03:35Z	-
dc.date	2012-03-29T22:03:35Z	-
dc.date	2000-10-31	-
dc.date.accessioned	2013-01-16T16:42:30Z	-
dc.date.available	2013-01-16T16:42:30Z	-
dc.date.issued	2013-01-16	-
dc.identifier	Structural Chemistry, Vol. 12, No. 1, 2001	-
dc.identifier	http://hdl.handle.net/123456789/1234	-
dc.identifier.uri	http://www.repositoriodigital.ipn.mx/handle/123456789/11695	-
dc.description	Cadmium hexacyanometallates (II) crystallize in the same monoclinic cell (space group C52 h−P21/ n) reported for the analogs of manganous complexes. In that monoclinic framework, two outer cations (M c Mn2+ or Cd2+) of neighboring structural units M2[LII(CN)6], (L c FeII, RuII, OsII), are linked by two common water molecules. On heating above 1008C, these water bridges are removed. In dehydrated complexes, the outer cation (M) remains linked to only three CN ligands. The loss of aquo-ligands induces a remarkable p-back donation from the inner cation (L) to CN ligands, which was studied using IR, Raman, and M¨ossbauer spectroscopies.	-
dc.language	en	-
dc.publisher	Structural Chemistry	-
dc.subject	Hexacyanometallate	-
dc.subject	X-ray diffraction	-
dc.subject	IR spectra	-
dc.subject	Raman spectra	-
dc.subject	M¨ossbauer spectra	-
dc.title	Structural Characterization of Cadmium Hexacyanometallates(II) and Related Complexes	-
dc.type	Article	-
Aparece en las colecciones:	Doctorado

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