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Título : MoÈ ssbauer spectra of ferrous salts of transition metal cyano complexes. A survey
Fecha de publicación : 16-ene-2013
Editorial : Transition Met. Chem
Descripción : Ferrous salts of ten hexacyanometallates and three tetracyanometallates were obtained and their MoÈ ss- bauer spectra interpreted according to recent structural models for these families of compounds. Ferrous fer- rocyanide (Williamson White) and its ruthenium and osmium analogs prepared mechanochemically are stable for hours, allowing their study by MoÈ ssbauer spectros- copy and other related techniques. For ferrous salts of trivalent hexacyanometallate anions, the random dis- tribution of anion vacancies is discarded and a model of two well de®ned relative positions of CN and H2O ligands around the Fe2+ is suggested. Iron was found octahedrally coordinated in tetracyanometallates.
URI : http://www.repositoriodigital.ipn.mx/handle/123456789/11713
Otros identificadores : Transition Met. Chem., 24, 163±167 (1999)
Aparece en las colecciones: Doctorado

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