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Título : Structural Characterization of Cadmium Hexacyanometallates(II) and Related Complexes
Palabras clave : Hexacyanometallate
X-ray diffraction
IR spectra
Raman spectra
M¨ossbauer spectra
Fecha de publicación : 16-ene-2013
Editorial : Structural Chemistry
Descripción : Cadmium hexacyanometallates (II) crystallize in the same monoclinic cell (space group C52 h−P21/ n) reported for the analogs of manganous complexes. In that monoclinic framework, two outer cations (M c Mn2+ or Cd2+) of neighboring structural units M2[LII(CN)6], (L c FeII, RuII, OsII), are linked by two common water molecules. On heating above 1008C, these water bridges are removed. In dehydrated complexes, the outer cation (M) remains linked to only three CN ligands. The loss of aquo-ligands induces a remarkable p-back donation from the inner cation (L) to CN ligands, which was studied using IR, Raman, and M¨ossbauer spectroscopies.
URI : http://www.repositoriodigital.ipn.mx/handle/123456789/11695
Otros identificadores : Structural Chemistry, Vol. 12, No. 1, 2001
Aparece en las colecciones: Doctorado

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