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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Cruz López, María del Carmen | - |
dc.date.accessioned | 2013-01-30T17:03:25Z | - |
dc.date.available | 2013-01-30T17:03:25Z | - |
dc.date.issued | 2013-01-30 | - |
dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/12369 | - |
dc.description | A NewSynthetic Route of 2-Aroyl- and 2-Benzyl-Benzofurans and their Application in the Total Synthesis of a Metabolite Isolated from Dorstenia gigas | es |
dc.description.abstract | The Lewis acid-catalyzed cyclization of the (Z)-3-(dimethylamino)-2-aryloxy-1-arylprop-2-en-1-ones 4a–h leads to a regioselective and short synthesis of 2-aroylbenzofurans 2a–h. TheWolff–Kishner reduction of the latter yielded a series of substituted 2-benzylbenzofurans 3a–h. This methodology was applied in the first total synthesis of the metabolite 2-(4-hydroxybenzyl)-6-methoxybenzofuran 1, which was isolated from the tropical plant Dorstenia gigas, and obtained through a six-step route and in a 24% overall yield. | es |
dc.description.sponsorship | Instituto Politécnico Nacional CIBA-Tlaxcala | es |
dc.subject | Dorstenia gigas | es |
dc.title | A NewSynthetic Route of 2-Aroyl- and 2-Benzyl-Benzofurans and their Application in the Total Synthesis of a Metabolite Isolated from Dorstenia gigas | es |
dc.type | Article | es |
dc.description.especialidad | Medico-Biológicas | es |
dc.description.tipo | es | |
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Art_Aus J Chem 2008, 61(12), 991-999-1a.pdf | 92.26 kB | Adobe PDF | Visualizar/Abrir |
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